FREE EXPANSION JET SOURCES AND THE MBE GROWTH OF GaN

A. M. Johnston, D. E. Crawford, R. Held, A. M. Dabiran, and P. I. Cohen
University of Minnesota, Minneapolis, MN 55455

42nd AVS National Symposium, October 16-20, 1995, Electronic Materials & Processing Session EM-MoM

Abstract

Free expansion jet sources can produce directed, energetic beams of gas molecules at high fluxes. A jet which reduces the gas load on the MBE growth chamber and which can be mounted into a standard source port is presented. It incorporates differential pumping via a liquid nitrogen cryopump coil and skimmer. The jet has been used with NH_3 to grow GaN on (0001) sapphire and (001) MgO. Growth rates exceeding 0.3 um/hr at substrate temperatures of 780 degree C and background pressures of less than 10^(-8) torr have been obtained. At comparable incident flux densities the background pressures are between 4 and 10 times lower than those achieved using a dosing tube pointed directly at the sample. Incident NH_3 fluxes corresponding to beam equivalent pressures of 5x10^(-5) torr are typical. At high nozzle pressures the flux begins to roll off because of scattering with background gases between the nozzle and skimmer. NH_3 condensation on the skimmer and nozzle is inhibited using electrical heaters. However, dissociation of NH_3 on the exposed nozzle filaments limits the maximum nozzle temperature to 400 degree C. The dissociated NH_3 leaves the jet as N_2 and H_2 and adversely affects the jet performance.

This work was partially supported by the ONR (N00014-93-1-0241) and AFOSR (F49620-93-1-0080).


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